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Russian Coatings Journal

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No 9 (2023)
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NEWS

 
4-9 35
 
60 34

PROCESSING OF POLYMERS AND COMPOSITES

24-28 52
Abstract

The article provides information that ethyl silicate-32 performs in polyvinyl acetate dispersion the function of a coalescent during film formation, an elasticizer during the operation of products, as well as a substance that increases strength.

45-56 54
Abstract

The paper considers the basic rules for formulating solvent based coatings for general industrial purposes. The classification of recipes is given. Using the combined method, the formulation of uralkid enamel of the business category was calculated. A computer program for calculating the formulations of solvent based coatings for general industrial purposes has been developed.

DISCUSSION CLUB

CHEMICAL TECHNOLOGIES

29-36 45
Abstract

The adsorption of special additives containing different functional groups: acidic, alkaline and quaternary ammonium — from solutions in xylene was studied on samples of titanium dioxide used in the domestic coatings industry. The areas occupied by additive molecules in a dense monolayer on the TiO2 surface are calculated. It is shown that the maximum values of adsorption are observed in the case of an additive having a basic character, and the minimum values in the case of a quaternary amine. The largest value of the main additive is explained by the presence of modifiers in TiO2 samples — oxides of amphoteric metals (Al2O3, SiO2, ZrO2) capable of showing acid-base properties. In this case, simultaneously with the physical adsorption of the solute, chemoadsorption takes place due to strong Lewis acid centers. The smaller value of the acidic additive indicates both weak chemisorption due to weaker main centers, and a weakening of physical adsorption due to the displacement of the additive from the surface of TiO2 by solvent molecules. In the case of quaternary amine, chemisorption is absent and only physical adsorption is observed, weakened by competing solvent adsorption, the value of which is almost the same for all TiO2 samples. The largest amount of adsorption of basic and acidic additives is observed in the case of TiO2 samples obtained by the chloride method. In relation to the main additive, TiO2 samples of the following brands show the greatest activity: R-706, R-966, R-280, R-902, BLR-699.

STANDARDIZATION AND METROLOGY

37-44 44
Abstract

The American standard UL-263 for testing building structures and materials for fire resistance is considered. The temperature-time curves of various fire regimes are shown. Special equipment that allows you to test materials under preload was studied. The parameters for which this method is tested are shown. Additional tests of fire-resistant materials with subsequent exposure to a water jet of a fire nozzle are described.

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ISSN 0130-9013 (Print)