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Protective electric insulation coatings based on cationic-curing epoxypolyurethane compositions

Abstract

New hybrid polymatrix epoxy-polyurethane compositions have been synthesized by simultaneously using two binders of different natures — diane epoxy resin and polyurethane quasi-prepolymer Gekkon-P100 based on aromatic isocyanates, and using a cationic hardener — a boron trifluoride-ether complex mixed with trichloropropyl phosphate and diethylene glycol. The results of a study of the physico-mechanical and electrophysical properties of the obtained coatings, both cold and hot curing, depending on the ratio of the epoxy and polyurethane components and the amount of hardener are presented.

About the Authors

I. B. Glebova
I. V. Grebenshchikov Institute of Silicate Chemistry, a branch of the B. P. Konstantinov St. Petersburg Institute of Nuclear Physics, Kurchatov Institute
Russian Federation

199034, St. Petersburg, nab. Makarova, 2



G. S. Sokolov
I. V. Grebenshchikov Institute of Silicate Chemistry, a branch of the B. P. Konstantinov St. Petersburg Institute of Nuclear Physics, Kurchatov Institute; Glass System LLC
Russian Federation

199034, St. Petersburg, nab. Makarova, 2

Novosaratovka, Vsevolozhsky district, Leningrad Region, 188644 Oktyabrskaya Embankment, 31



V. M. Mikhalchuk
Donetsky State University
Russian Federation

Prof.

283001, Donetsk, Universitetskaya str., 24



S. G. Grinik
Glass System LLC
Russian Federation

Novosaratovka, Vsevolozhsky district, Leningrad Region, 188644 Oktyabrskaya Embankment, 31



O. A. Shilova
I. V. Grebenshchikov Institute of Silicate Chemistry, a branch of the B. P. Konstantinov St. Petersburg Institute of Nuclear Physics, Kurchatov Institute
Russian Federation

Prof.

199034, St. Petersburg, nab. Makarova, 2



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Review

For citations:


Glebova I.B., Sokolov G.S., Mikhalchuk V.M., Grinik S.G., Shilova O.A. Protective electric insulation coatings based on cationic-curing epoxypolyurethane compositions. Russian Coatings Journal. 2025;(7-8):36-41. (In Russ.)

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