Protective electric insulation coatings based on cationic-curing epoxypolyurethane compositions
Abstract
New hybrid polymatrix epoxy-polyurethane compositions have been synthesized by simultaneously using two binders of different natures — diane epoxy resin and polyurethane quasi-prepolymer Gekkon-P100 based on aromatic isocyanates, and using a cationic hardener — a boron trifluoride-ether complex mixed with trichloropropyl phosphate and diethylene glycol. The results of a study of the physico-mechanical and electrophysical properties of the obtained coatings, both cold and hot curing, depending on the ratio of the epoxy and polyurethane components and the amount of hardener are presented.
About the Authors
I. B. GlebovaRussian Federation
199034, St. Petersburg, nab. Makarova, 2
G. S. Sokolov
Russian Federation
199034, St. Petersburg, nab. Makarova, 2
Novosaratovka, Vsevolozhsky district, Leningrad Region, 188644 Oktyabrskaya Embankment, 31
V. M. Mikhalchuk
Russian Federation
Prof.
283001, Donetsk, Universitetskaya str., 24
S. G. Grinik
Russian Federation
Novosaratovka, Vsevolozhsky district, Leningrad Region, 188644 Oktyabrskaya Embankment, 31
O. A. Shilova
Russian Federation
Prof.
199034, St. Petersburg, nab. Makarova, 2
References
1. Bahramnia H., Semnani H.M., Habibolahzadeh A., Abdoos H. Epoxy/polyurethane nanocompositecoatings for anti-erosion/ wearapplications: A review // J. Comp. Mater. 2020. Vol. 54, No. 22. P. 3189–3203. DOI: 10.1177/0021998320908299
2. Bahramnia H., Semnani H.M., Habibolahzadeh A., Abdoos H. Epoxy/polyurethane hybrid nanocomposite coatings reinforced with MWCNTs and SiO2 nanoparticles: Processing, mechanical properties and wear behavior // Surf. Coat. Technol. 2021. Vol. 415. 127121. https://doi.org/10.1016/j.surfcoat.2021.127121
3. Кузнецова В.А., Силаева А.А., Железняк В.Г., Марченко С.А. Модификация эпоксидных пленкообразующих и отвердителей, применяемых для лакокрасочных покрытий (обзор) // Труды ВИАМ. 2022. Т. 111, № 5. С. 96–111. Ст. 09. DOI: 10.18577/2307-6046-20220-5-96-111
4. Bratasyuk N.A., Zuev V.V.Cure kinetics of epoxyurethane compositions with amine hardeners of various nature // Rus. J. ApplI. Chem. 2020. Vol. 93, No. 10. P. 1504–1517. DOI: 10.1134/S1070427220100043.
5. Зиновьева Е.Г., Ефимов В.А., Кольцов Н.И. Комплексы кислот Льюиса с трис (галоген) алкилфосфатами — новые отвердители эпоксидных смол // Пластические массы. 2008. № 2. С. 32–33.
6. Pan C.Y., Qi L.W., Liu Y. Properties’ improvement of epoxy resin using prepolymers prepared from diisocyanates and 3,9-dihydroxyethyl-3,9-dibenzyl-1,5,7,11-tetraoxaspiro(5,5) undecane // Eur. Polym. J. 1999. Vol. 35, No. 10. P. 1813–1819. DOI: 10.1016/S0014-3057(98)00266-3
7. Getmanchuk Y.P., Mokrinskaya E.V., Yukhimets A.Y. Cationic polymerization of glycidyl ethers // Polym. Sci. Ser. B. 2004. Vol. 46, No. 7–8. P. 230–232.
8. Красильникова Л.Н., Алексеев В.А., Шилова О.А. Влияние отвердителей на физико-механические свойства термостойких органосиликатных покрытий // Лакокрасочные материалы и их применение. 2025. № 1–2 (571). С. 32–38.
Review
For citations:
Glebova I.B., Sokolov G.S., Mikhalchuk V.M., Grinik S.G., Shilova O.A. Protective electric insulation coatings based on cationic-curing epoxypolyurethane compositions. Russian Coatings Journal. 2025;(7-8):36-41. (In Russ.)
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