lkmipЛакокрасочные материалы и их применениеRussian Coatings Journal0130-9013Paint-Media LLClkmip-329Research ArticleЗАЩИТА ОТ КОРРОЗИИCORROSION PROTECTIONИнгибирующие компоненты лакокрасочных покрытий с контролируемой противокоррозионной активностьюInhibiting components of coatings with controlled anticorrosion activityСтепинС. Н.StepinS. N.

Профессор, д.х.н. 

420111, Казань, ул. Карла Маркса, 68

Doctor of Chem. Sci., Prof.

420111, Kazan, Karl Marx str., 68

stepin_1949@mail.ruСороковА. В.SorokovA. V.

доцент, к.т.н.

420111, Казань, ул. Карла Маркса, 68

Associate Prof., Candidate of Tech. Sci.

420111, Kazan, Karl Marx str., 68

МининМ. А.MininM. A.

магистрант

420111, Казань, ул. Карла Маркса, 68

undergraduate

420111, Kazan, Karl Marx str., 68

СучковВ. С.SuchkovV. S.

ст. преподаватель

420111, Казань, ул. Карла Маркса, 68

Senior lecturer

420111, Kazan, Karl Marx str., 68

Казанский национальный исследовательский технологический университет, кафедра плазмохимических технологий наноматериалов и покрытийРоссияKazan National Research Technological University, Department of Plasma Chemical Technologies of Nanomaterials and CoatingsRussian Federation202507062026094350Copyright © Paint-Media LLC, 20262026Paint-Media LLCPaint-Media LLChttps://www.lkmprim.ru/jour/about/submissions#copyrightNoticehttps://www.lkmprim.ru/jour/article/view/329

Рассмотрены особенности использования в качестве компонентов лакокрасочных покрытий ингибиторов коррозии, иммобилизация и капсулирование как способы регулирования активности ингибирующих компонентов в подавлении коррозии окрашенных металлов.

Features of using corrosion inhibitors as components of paint coatings are considered, immobilization and encapsulation as methods for regulating the activity of inhibiting components in suppressing the corrosion of painted metals.

ингибиторы коррозии покрытияиммобилизациякапсуляция.corrosion inhibitors coatingimmobilizationencapsulation.ReferencesFreitag W., Stoye D. (ed.). Paints, coatings and solvents. John Wiley & Sons, 2008.Freitag W., Stoye D. (ed.). Paints, coatings and solvents. John Wiley & Sons, 2008.Vogelsang J.A. Anticorrosive pigments in organic coatings // Self-healing properties of new surface treatments EFC.2011. Vol. 58. Р. 1.Vogelsang J.A. Anticorrosive pigments in organic coatings // Self-healing properties of new surface treatments EFC.2011. Vol. 58. Р. 1.Petrunin M.A. Advances in anti-corrosion polymeric and paint coatings on metals: Preparation, adhesion, characterization and application // Metals. 2022. Vol. 12, N 7. P. 1216.Petrunin M.A. Advances in anti-corrosion polymeric and paint coatings on metals: Preparation, adhesion, characterization and application // Metals. 2022. Vol. 12, N 7. P. 1216.Giaveri S., Gronchi P., Barzoni A. IPN polysiloxane-epoxy resin for high temperature coatings: structure effects on layer performance after 450 C treatment // Coatings. 2017. Vol. 7, N 12. P. 213.Giaveri S., Gronchi P., Barzoni A. IPN polysiloxane-epoxy resin for high temperature coatings: structure effects on layer performance after 450 C treatment // Coatings. 2017. Vol. 7, N 12. P. 213.Petrunin M.A. Advances in anti-corrosion polymeric and paint coatings on metals: Preparation, adhesion, characterization and application // Metals. 2022. Vol. 12, N 7. P. 1216.Petrunin M.A. Advances in anti-corrosion polymeric and paint coatings on metals: Preparation, adhesion, characterization and application // Metals. 2022. Vol. 12, N 7. P. 1216.Deflorian F., Fedel M., Gelling V.J. New Pigments and Additives for Corrosion Protection by Organic Coatings // Frontiers in Materials. 2020. Vol. 7. P. 606256.Deflorian F., Fedel M., Gelling V.J. New Pigments and Additives for Corrosion Protection by Organic Coatings // Frontiers in Materials. 2020. Vol. 7. P. 606256.Asaldoust S., Ramezanzadeh B. Synthesis and characterization of a high-quality nanocontainer based on benzimidazole-zinc phosphate (ZP-BIM) tailored graphene oxides; a facile approach to fabricating a smart self-healing anti-corrosion system // Journal of Colloid and Interface Science. 2020. Vol. 564. P. 230–44.Asaldoust S., Ramezanzadeh B. Synthesis and characterization of a high-quality nanocontainer based on benzimidazole-zinc phosphate (ZP-BIM) tailored graphene oxides; a facile approach to fabricating a smart self-healing anti-corrosion system // Journal of Colloid and Interface Science. 2020. Vol. 564. P. 230–44.Pokhmurs’kyi V.I., Kwiatkowski L., Zin’ I.M. et al. Corrosion protection of aluminum alloys by inhibiting pigments // Materials Science. 2006. Vol. 42, N 5. P. 573–8.Pokhmurs’kyi V.I., Kwiatkowski L., Zin’ I.M. et al. Corrosion protection of aluminum alloys by inhibiting pigments // Materials Science. 2006. Vol. 42, N 5. P. 573–8.Hernandez M. et al. Effect of an inhibitive pigment zinc-aluminum-phosphate (ZAP) on the corrosion mechanisms of steel in waterborne coatings // Progress in organic coatings. 2006. Vol. 56, N 2–3. P. 199–206.Hernandez M. et al. Effect of an inhibitive pigment zinc-aluminum-phosphate (ZAP) on the corrosion mechanisms of steel in waterborne coatings // Progress in organic coatings. 2006. Vol. 56, N 2–3. P. 199–206.Bethencourt M., Botana F. J., Marcos M. et al. Inhibitor properties of “green” pigments for paints // Progress in Organic Coatings. 2003. Vol. 46, N 4. P. 280–7.Bethencourt M., Botana F. J., Marcos M. et al. Inhibitor properties of “green” pigments for paints // Progress in Organic Coatings. 2003. Vol. 46, N 4. P. 280–7.Alibakhshi E., Ghasemi E., Mahdavian M. Optimization of potassium zinc phosphate anticorrosion pigment by Taguchi experimental design // Progress in Organic Coatings. 2013. Vol. 76, N 1. P. 224–30.Alibakhshi E., Ghasemi E., Mahdavian M. Optimization of potassium zinc phosphate anticorrosion pigment by Taguchi experimental design // Progress in Organic Coatings. 2013. Vol. 76, N 1. P. 224–30.Olivieri F., Castaldo R., Cocca M. et al. Mesoporous silica nanoparticles as carriers of active agents for smart anticorrosive organic coatings: a critical review // Nanoscale. 2021. Vol. 13, N 20. P. 9091–111.Olivieri F., Castaldo R., Cocca M. et al. Mesoporous silica nanoparticles as carriers of active agents for smart anticorrosive organic coatings: a critical review // Nanoscale. 2021. Vol. 13, N 20. P. 9091–111.An S., Lee M.W., Yarin A.L. et al. A review on corrosion-protective extrinsic self-healing: Comparison of microcapsule-based systems and those based on core-shell vascular networks // Chemical Engineering Journal. 2018. Vol. 344. P. 206–20.An S., Lee M.W., Yarin A.L. et al. A review on corrosion-protective extrinsic self-healing: Comparison of microcapsule-based systems and those based on core-shell vascular networks // Chemical Engineering Journal. 2018. Vol. 344. P. 206–20.Ferrer E.L., Rollon A.P., Mendoza H.D. et al. Double-doped zeolites for corrosion protection of aluminium alloys // Microporous and Mesoporous Materials. 2014. Vol. 188. P. 8–15.Ferrer E.L., Rollon A.P., Mendoza H.D. et al. Double-doped zeolites for corrosion protection of aluminium alloys // Microporous and Mesoporous Materials. 2014. Vol. 188. P. 8–15.Denissen P.J., Homborg A.M., Garcia S.J. Requirements for corrosion inhibitor release from damaged primers for stable protection: a simulation and experimental approach using cerium loaded carriers // Surface and Coatings Technology. 2022. Vol. 430. P. 127966.Denissen P.J., Homborg A.M., Garcia S.J. Requirements for corrosion inhibitor release from damaged primers for stable protection: a simulation and experimental approach using cerium loaded carriers // Surface and Coatings Technology. 2022. Vol. 430. P. 127966.Raj R., Morozov Y., Calado L. M. et al. Calcium carbonate particles loaded with triethanolamine and polyethylenimine for enhanced corrosion protection of epoxy coated steel // Corrosion Science. 2020. Vol. 167. P. 108548.Raj R., Morozov Y., Calado L. M. et al. Calcium carbonate particles loaded with triethanolamine and polyethylenimine for enhanced corrosion protection of epoxy coated steel // Corrosion Science. 2020. Vol. 167. P. 108548.Dariva C.G., Galio A.F. Corrosion inhibitors-principles, mechanisms and applications // Developments in corrosion protection. 2014. Vol. 16. P. 365–78.Dariva C.G., Galio A.F. Corrosion inhibitors-principles, mechanisms and applications // Developments in corrosion protection. 2014. Vol. 16. P. 365–78.Lamaka S.V., Zheludkevich M.L., Yasakau K.A. et al. High effective organic corrosion inhibitors for 2024 aluminium alloy // Electrochimica Acta. 2007. Vol. 52, N 25. P. 7231–47.Lamaka S.V., Zheludkevich M.L., Yasakau K.A. et al. High effective organic corrosion inhibitors for 2024 aluminium alloy // Electrochimica Acta. 2007. Vol. 52, N 25. P. 7231–47.Obot I.B., Macdonald D.D., Gasem Z.M. Density functional theory (DFT) as a powerful tool for designing new organic corrosion inhibitors. Part 1: an overview // Corrosion Science. 2015. Vol. 99. P. 1–30.Obot I.B., Macdonald D.D., Gasem Z.M. Density functional theory (DFT) as a powerful tool for designing new organic corrosion inhibitors. Part 1: an overview // Corrosion Science. 2015. Vol. 99. P. 1–30.Li D., Zhang Z., Sukhbat B., et al. Smart inhibitor systems towards anti-corrosion: design and applications // RSC Applied Polymers. 2025. Vol. 3, N 3. P. 532–48.Li D., Zhang Z., Sukhbat B., et al. Smart inhibitor systems towards anti-corrosion: design and applications // RSC Applied Polymers. 2025. Vol. 3, N 3. P. 532–48.Denissen P.J., Homborg A.M., Garcia S.J. Requirements for corrosion inhibitor release from damaged primers for stable protection: a simulation and experimental approach using cerium loaded carriers // Surface and Coatings Technology. 2022. Vol. 430. P. 127966.Denissen P.J., Homborg A.M., Garcia S.J. Requirements for corrosion inhibitor release from damaged primers for stable protection: a simulation and experimental approach using cerium loaded carriers // Surface and Coatings Technology. 2022. Vol. 430. P. 127966.Soleymanibrojeni M., Shi H., Udoh I.I. et al. Microcontainers with 3-amino-1, 2, 4-triazole-5-thiol for enhancing anticorrosion waterborne coatings for AA2024-T3 // Progress in Organic Coatings. 2019. Vol. 137. P. 105336.Soleymanibrojeni M., Shi H., Udoh I.I. et al. Microcontainers with 3-amino-1, 2, 4-triazole-5-thiol for enhancing anticorrosion waterborne coatings for AA2024-T3 // Progress in Organic Coatings. 2019. Vol. 137. P. 105336.Qian B., Michailidis M., Bilton M. et al. Tannic complexes coated nanocontainers for controlled release of corrosion inhibitors in self-healing coatings // Electrochimica Acta. 2019. Vol. 297. P. 1035–41.Qian B., Michailidis M., Bilton M. et al. Tannic complexes coated nanocontainers for controlled release of corrosion inhibitors in self-healing coatings // Electrochimica Acta. 2019. Vol. 297. P. 1035–41.Suryanarayana C., Rao K.C., Kumar D. Preparation and characterization of microcapsules containing linseed oil and its use in self-healing coatings // Progress in organic coatings. 2008. Vol. 63, N. 1. P. 72–8.Suryanarayana C., Rao K.C., Kumar D. Preparation and characterization of microcapsules containing linseed oil and its use in self-healing coatings // Progress in organic coatings. 2008. Vol. 63, N. 1. P. 72–8.Montemor M.F. Hybrid nanocontainer-based smart self-healing composite coatings for the protection of metallic assets // Smart Composite Coatings and Membranes. Woodhead Publishing, 2016. P. 183–209.Montemor M.F. Hybrid nanocontainer-based smart self-healing composite coatings for the protection of metallic assets // Smart Composite Coatings and Membranes. Woodhead Publishing, 2016. P. 183–209.Zheludkevich M.L., Tedim J., Ferreira M.G.S. “Smart” coatings for active corrosion protection based on multi-functional micro and nanocontainers // Electrochimica Acta. 2012. Vol. 82. P. 314–23.Zheludkevich M.L., Tedim J., Ferreira M.G.S. “Smart” coatings for active corrosion protection based on multi-functional micro and nanocontainers // Electrochimica Acta. 2012. Vol. 82. P. 314–23.Montemor M.F. Functional and smart coatings for corrosion protection: A review of recent advances // Surface and Coatings Technology. 2014. Vol. 258. P. 17–37.Montemor M.F. Functional and smart coatings for corrosion protection: A review of recent advances // Surface and Coatings Technology. 2014. Vol. 258. P. 17–37.Denissen P.J., Homborg A.M., Garcia S.J. Requirements for corrosion inhibitor release from damaged primers for stable protection: a simulation and experimental approach using cerium loaded carriers // Surface and Coatings Technology. 2022. Vol.430. P. 127966.Denissen P.J., Homborg A.M., Garcia S.J. Requirements for corrosion inhibitor release from damaged primers for stable protection: a simulation and experimental approach using cerium loaded carriers // Surface and Coatings Technology. 2022. Vol.430. P. 127966.Borisova D., Akçakayıran D., Schenderlein M. et al.Nanocontainer-based anticorrosive coatings: effect of the container size on the self-healing performance // Advanced Functional Materials. 2013. Vol. 23, N. 30. P. 3799–3812.Borisova D., Akçakayıran D., Schenderlein M. et al.Nanocontainer-based anticorrosive coatings: effect of the container size on the self-healing performance // Advanced Functional Materials. 2013. Vol. 23, N. 30. P. 3799–3812.Snihirova D., Lamaka S.V., Montemor M.F. “SMART” protective ability of water based epoxy coatings loaded with CaCO3 microbeads impregnated with corrosion inhibitors applied on AA2024 substrates // Electrochimica Acta. 2012. Vol. 83. P. 439–47.Snihirova D., Lamaka S.V., Montemor M.F. “SMART” protective ability of water based epoxy coatings loaded with CaCO3 microbeads impregnated with corrosion inhibitors applied on AA2024 substrates // Electrochimica Acta. 2012. Vol. 83. P. 439–47.Denissen P.J., Shkirskiy V., Volovitch P. et al. Corrosion inhibition at scribed locations in coated AA2024-T3 by cerium-and DMTD-loaded natural silica microparticles under continuous immersion and wet/dry cyclic exposure // ACS applied materials & interfaces. 2020. Vol. 12, N. 20. P. 23417–31.Denissen P.J., Shkirskiy V., Volovitch P. et al. Corrosion inhibition at scribed locations in coated AA2024-T3 by cerium-and DMTD-loaded natural silica microparticles under continuous immersion and wet/dry cyclic exposure // ACS applied materials & interfaces. 2020. Vol. 12, N. 20. P. 23417–31.Denissen P.J., Garcia S.J. Cerium-loaded algae exoskeletons for active corrosion protection of coated AA2024-T3 // Corrosion Science. 2017. Vol. 128. P. 164–75.Denissen P.J., Garcia S.J. Cerium-loaded algae exoskeletons for active corrosion protection of coated AA2024-T3 // Corrosion Science. 2017. Vol. 128. P. 164–75.Snihirova D., Lamaka S. V., Taheri P., Mol J. M. C., Montemor M. F. Comparison of the synergistic effects of inhibitor mixtures tailored for enhanced corrosion protection of bare and coated AA2024-T3 //Surface and Coatings Technology. – 2016. Т. 303. С. 342-351.Snihirova D., Lamaka S. V., Taheri P., Mol J. M. C., Montemor M. F. Comparison of the synergistic effects of inhibitor mixtures tailored for enhanced corrosion protection of bare and coated AA2024-T3 //Surface and Coatings Technology. – 2016. Т. 303. С. 342-351.Raj R., Morozov Y., Calado L. M., Taryba M. G., Kahraman R., Shakoor A., Montemor M. F. Inhibitor loaded calcium carbonate microparticles for corrosion protection of epoxy-coated carbon steel //Electrochimica Acta. – 2019. – Vol. 319. – С. 801-812.Raj R., Morozov Y., Calado L. M., Taryba M. G., Kahraman R., Shakoor A., Montemor M. F. Inhibitor loaded calcium carbonate microparticles for corrosion protection of epoxy-coated carbon steel //Electrochimica Acta. – 2019. – Vol. 319. – С. 801-812.Raj R. et al. Calcium carbonate particles loaded with triethanolamine and polyethylenimine for enhanced corrosion protection of epoxy coated steel // Corrosion Science. 2020. Vol. 167. З. 108548.Raj R. et al. Calcium carbonate particles loaded with triethanolamine and polyethylenimine for enhanced corrosion protection of epoxy coated steel // Corrosion Science. 2020. Vol. 167. З. 108548.Morozov Y., Montemor M. F. Polyethyleneimine as corrosion inhibitor against chloride-induced corrosion of mild steel // European Corrosion Congress, EUROCORR 2015. Austrian Society for Metallurgy and Materials (ASMET), 2015. Р. 1892.Morozov Y., Montemor M. F. Polyethyleneimine as corrosion inhibitor against chloride-induced corrosion of mild steel // European Corrosion Congress, EUROCORR 2015. Austrian Society for Metallurgy and Materials (ASMET), 2015. Р. 1892.Choi H., Song Y.K., Kim K.Y. et al. Encapsulation of triethanolamine as organic corrosion inhibitor into nanoparticles and its active corrosion protection for steel sheets // Surface and Coatings Technology. 2012. Vol. 206, N. 8–9. P. 2354–62.Choi H., Song Y.K., Kim K.Y. et al. Encapsulation of triethanolamine as organic corrosion inhibitor into nanoparticles and its active corrosion protection for steel sheets // Surface and Coatings Technology. 2012. Vol. 206, N. 8–9. P. 2354–62.Zhao J., Santoso A., Garcia S.J. Small concentrations of NaCl help building stable inhibiting layers from 2, 5-dimercapto-1, 3, 4-thiadiazole (DMTD) on AA2024-T3 // Corrosion Science. 2023. Vol. 225. P. 111562.Zhao J., Santoso A., Garcia S.J. Small concentrations of NaCl help building stable inhibiting layers from 2, 5-dimercapto-1, 3, 4-thiadiazole (DMTD) on AA2024-T3 // Corrosion Science. 2023. Vol. 225. P. 111562.Zhao J., Na D.H., Garcia S.J. Surface modification of natural porous silica microparticles to control the loading and release of organic corrosion inhibitors in coatings // NPG Asia Materials. 2025. Vol. 17, N. 1. P. 27.Zhao J., Na D.H., Garcia S.J. Surface modification of natural porous silica microparticles to control the loading and release of organic corrosion inhibitors in coatings // NPG Asia Materials. 2025. Vol. 17, N. 1. P. 27.Ollik K., Lieder M. Review of the application of graphenebased coatings as anticorrosion layers // Coatings. 2020. Vol. 10, N. 9. P. 883.Ollik K., Lieder M. Review of the application of graphenebased coatings as anticorrosion layers // Coatings. 2020. Vol. 10, N. 9. P. 883.Fazli-Shokouhi S., Nasirpouri F., Khatamian M. Polyanilinemodified graphene oxide nanocomposites in epoxy coatings for enhancing the anticorrosion and antifouling properties // Journal of Coatings Technology and Research. 2019. Vol. 16, N. 4. P. 983–97.Fazli-Shokouhi S., Nasirpouri F., Khatamian M. Polyanilinemodified graphene oxide nanocomposites in epoxy coatings for enhancing the anticorrosion and antifouling properties // Journal of Coatings Technology and Research. 2019. Vol. 16, N. 4. P. 983–97.Deshpande P.P., Vathare S.S., Vagge S.T. et al. Conducting polyaniline/multi-wall carbon nanotubes composite paints on low carbon steel for corrosion protection: electrochemical investigations // Chemical Papers. 2013. Vol. 67, N. 8. P. 1072–8.Deshpande P.P., Vathare S.S., Vagge S.T. et al. Conducting polyaniline/multi-wall carbon nanotubes composite paints on low carbon steel for corrosion protection: electrochemical investigations // Chemical Papers. 2013. Vol. 67, N. 8. P. 1072–8.Maia F.C. Micro/nanoreservoirs for controlled release of active species in smart functional coatings: дис. Universidade de Aveiro (Portugal), 2015.Maia F.C. Micro/nanoreservoirs for controlled release of active species in smart functional coatings: дис. Universidade de Aveiro (Portugal), 2015.Ou Y.X., Wang H.Q., Ouyang X. et al. Recent advances and strategies for high-performance coatings // Progress in Materials Science. 2023. Vol. 136. P. 101125.Ou Y.X., Wang H.Q., Ouyang X. et al. Recent advances and strategies for high-performance coatings // Progress in Materials Science. 2023. Vol. 136. P. 101125.Borisova D., Möhwald H., Shchukin D.G. Mesoporous silica nanoparticles for active corrosion protection // ACS nano. 2011. Vol. 5, N. 3. P. 1939–46.Borisova D., Möhwald H., Shchukin D.G. Mesoporous silica nanoparticles for active corrosion protection // ACS nano. 2011. Vol. 5, N. 3. P. 1939–46.Kartsonakis I.A., Danilidis I.L., Pappas G.S. et al. Encapsulation and release of corrosion inhibitors into titania nanocontainers // Journal of Nanoscience and Nanotechnology. 2010. Vol. 10, N. 9. P. 5912–20.Kartsonakis I.A., Danilidis I.L., Pappas G.S. et al. Encapsulation and release of corrosion inhibitors into titania nanocontainers // Journal of Nanoscience and Nanotechnology. 2010. Vol. 10, N. 9. P. 5912–20.Tedim J., Zheludkevich M.L., Salak A.N. et al. Nanostructured LDH-container layer with active protection functionality // Journal of Materials Chemistry. 2011. Vol. 21, N. 39. P. 15464–70.Tedim J., Zheludkevich M.L., Salak A.N. et al. Nanostructured LDH-container layer with active protection functionality // Journal of Materials Chemistry. 2011. Vol. 21, N. 39. P. 15464–70.Lvov Y., Wang W., Zhang L. et al. Halloysite clay nanotubes for loading and sustained release of functional compounds // Advanced Materials. 2016. Vol. 28, N. 6. P. 1227–50.Lvov Y., Wang W., Zhang L. et al. Halloysite clay nanotubes for loading and sustained release of functional compounds // Advanced Materials. 2016. Vol. 28, N. 6. P. 1227–50.Shchukin D., Möhwald H. A coat of many functions // Science. 2013. Vol. 341, N. 6153. P. 1458–9.Shchukin D., Möhwald H. A coat of many functions // Science. 2013. Vol. 341, N. 6153. P. 1458–9.Shchukin D.G., Sukhorukov G.B. Nanoparticle synthesis in engineered organic nanoscale reactors // Advanced Materials. 2004. Vol. 16, N. 8. P. 671–82.Shchukin D.G., Sukhorukov G.B. Nanoparticle synthesis in engineered organic nanoscale reactors // Advanced Materials. 2004. Vol. 16, N. 8. P. 671–82.Latnikova A., Grigoriev D.O., Hartmann J., et al. Polyfunctional active coatings with damage-triggered water-repelling effect // Soft Matter. 2011. Vol. 7, N. 2. P. 369–72.Latnikova A., Grigoriev D.O., Hartmann J., et al. Polyfunctional active coatings with damage-triggered water-repelling effect // Soft Matter. 2011. Vol. 7, N. 2. P. 369–72.Latnikova A., Grigoriev D., Möhwald H. et al. Microgel containers for self-healing polymeric materials: morphology prediction and mechanism of formation // Polymer. 2015. Vol. 73. P. 183–94.Latnikova A., Grigoriev D., Möhwald H. et al. Microgel containers for self-healing polymeric materials: morphology prediction and mechanism of formation // Polymer. 2015. Vol. 73. P. 183–94.Zheng Z., Schenderlein M., Huang X., et al. Influence of functionalization of nanocontainers on self-healing anticorrosive coatings // ACS Applied Materials & Interfaces. 2015. Vol. 7, N. 41. P. 22756–66.Zheng Z., Schenderlein M., Huang X., et al. Influence of functionalization of nanocontainers on self-healing anticorrosive coatings // ACS Applied Materials & Interfaces. 2015. Vol. 7, N. 41. P. 22756–66.Calegari F., da Silva B.C., Tedim J. et al. Benzotriazole encapsulation in spray-dried carboxymethylcellulose microspheres for active corrosion protection of carbon steel // Progress in Organic Coatings. 2020. Vol. 138. P. 105329.Calegari F., da Silva B.C., Tedim J. et al. Benzotriazole encapsulation in spray-dried carboxymethylcellulose microspheres for active corrosion protection of carbon steel // Progress in Organic Coatings. 2020. Vol. 138. P. 105329.Cavallaro G., Lazzara G., Fakhrullin R. Mesoporous inorganic nanoscale particles for drug adsorption and controlled release // Therapeutic Delivery. 2018. Vol. 9, N. 4. P. 287–301.Cavallaro G., Lazzara G., Fakhrullin R. Mesoporous inorganic nanoscale particles for drug adsorption and controlled release // Therapeutic Delivery. 2018. Vol. 9, N. 4. P. 287–301.Galvão T.L., Neves C.S., Caetano A.P. et al. Control of crystallite and particle size in the synthesis of layered double hydroxides: Macromolecular insights and a complementary modeling tool // Journal of Colloid and Interface Science. 2016. Vol. 468. P. 86–94.Galvão T.L., Neves C.S., Caetano A.P. et al. Control of crystallite and particle size in the synthesis of layered double hydroxides: Macromolecular insights and a complementary modeling tool // Journal of Colloid and Interface Science. 2016. Vol. 468. P. 86–94.Alibakhshi E., Ghasemi E., Mahdavian M. et al. A comparative study on corrosion inhibitive effect of nitrate and phosphate intercalated Zn–Al-layered double hydroxides (LDHs) nanocontainers incorporated into a hybrid silane layer and their effect on cathodic delamination of epoxy topcoat // Corrosion science. 2017. Vol. 115. P. 159–74.Alibakhshi E., Ghasemi E., Mahdavian M. et al. A comparative study on corrosion inhibitive effect of nitrate and phosphate intercalated Zn–Al-layered double hydroxides (LDHs) nanocontainers incorporated into a hybrid silane layer and their effect on cathodic delamination of epoxy topcoat // Corrosion science. 2017. Vol. 115. P. 159–74.Bohm S., McMurray H.N., Worsley D.A. et al. Novel environment friendly corrosion inhibitor pigments based on naturally occurring clay minerals // Materials and Corrosion. 2001. Vol. 52, N. 12. P. 896–903.Bohm S., McMurray H.N., Worsley D.A. et al. Novel environment friendly corrosion inhibitor pigments based on naturally occurring clay minerals // Materials and Corrosion. 2001. Vol. 52, N. 12. P. 896–903.Ghazi A., Ghasemi E., Mahdavian M., et al. The application of benzimidazole and zinc cations intercalated sodium montmorillonite as smart ion exchange inhibiting pigments in the epoxy ester coating // Corrosion Science. 2015. Vol. 94. P. 207–17.Ghazi A., Ghasemi E., Mahdavian M., et al. The application of benzimidazole and zinc cations intercalated sodium montmorillonite as smart ion exchange inhibiting pigments in the epoxy ester coating // Corrosion Science. 2015. Vol. 94. P. 207–17.Joussein E., Petit S., Churchman J. et al. Halloysite clay miner-als — a review // Clay minerals. 2005. Vol. 40, N. 4. P. 383–426.Joussein E., Petit S., Churchman J. et al. Halloysite clay miner-als — a review // Clay minerals. 2005. Vol. 40, N. 4. P. 383–426.Price R., Gaber B.P., Lvov Y.R. In vitro release characteristics of tetracycline HCl, khellin and nicotinamide adenine dineculeotide from halloysite; a cylindrical mineral // Journal of Microencapsulation. 2001. Vol. 18, N. 6. P. 713–22.Price R., Gaber B.P., Lvov Y.R. In vitro release characteristics of tetracycline HCl, khellin and nicotinamide adenine dineculeotide from halloysite; a cylindrical mineral // Journal of Microencapsulation. 2001. Vol. 18, N. 6. P. 713–22.Abdullayev E., Joshi A., Wei W. et al. Enlargement of halloysite clay nanotube lumen by selective etching of aluminum oxide // ACS nano. 2012. Vol. 6, N. 8. P. 7216–26.Abdullayev E., Joshi A., Wei W. et al. Enlargement of halloysite clay nanotube lumen by selective etching of aluminum oxide // ACS nano. 2012. Vol. 6, N. 8. P. 7216–26.Lvov Y.M., Shchukin D., Mohwald H. et al. Halloysite Clay Nanotubes for Controlled Release of Protective Agents // ACS Nano. 2008. Vol. 2. P. 814–20.Lvov Y.M., Shchukin D., Mohwald H. et al. Halloysite Clay Nanotubes for Controlled Release of Protective Agents // ACS Nano. 2008. Vol. 2. P. 814–20.Shchukina E., Grigoriev D., Sviridova T. et al. Comparative study of the effect of halloysite nanocontainers on autonomic corrosion protection of polyepoxy coatings on steel by salt-spray tests // Progress in Organic Coatings. 2017. Vol. 108. P. 84–9.Shchukina E., Grigoriev D., Sviridova T. et al. Comparative study of the effect of halloysite nanocontainers on autonomic corrosion protection of polyepoxy coatings on steel by salt-spray tests // Progress in Organic Coatings. 2017. Vol. 108. P. 84–9.Shchukin D.G., Möhwald H. Self-repairing coatings containing active nanoreservoirs // Small. 2007. Vol. 3, N. 6. З. 926–43. Grigoriev D., Shchukina E., Shchukin D.G. Nanocontainers for self-healing coatings // Advanced Materials Interfaces. 2017. Vol. 4, N. 1. Р. 1600318.Shchukin D.G., Möhwald H. Self-repairing coatings containing active nanoreservoirs // Small. 2007. Vol. 3, N. 6. З. 926–43. Grigoriev D., Shchukina E., Shchukin D.G. Nanocontainers for self-healing coatings // Advanced Materials Interfaces. 2017. Vol. 4, N. 1. Р. 1600318.

The authors declare that there are no conflicts of interest present.